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column 7 of the hazardous materials table

Transport in accordance with this special provision must be noted on the shipping paper. B49 Tanks equipped with interior heater coils are not authorized. 171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in 173.127. (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. The packaging shall be designed for a working temperature of at least 121 C (250 F). 130 Batteries, dry, sealed, n.o.s., commonly referred to as dry batteries, are hermetically sealed and generally utilize metals (other than lead) and/or carbon as electrodes. Nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel are not subject to the requirements of this special provision. If the SADT of the technically pure substance is higher than 75 C, the technically pure substance and formulations derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the requirements of this subchapter. 5 If this material meets the definition for a material poisonous by inhalation (see 171.8 of this subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate. B35 Tank cars containing hydrogen cyanide may be alternatively marked Hydrocyanic acid, liquefied if otherwise conforming to marking requirements in subpart D of this part. Determining Authorized Packaging for the Transportation of a Hazardous Where the subsidiary hazard material is Forbidden in column (9A) or (9B) of the 172.101 Table, the radioactive material may only be offered for transportation and transported by aircraft under conditions approved by the Associate Administrator. While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate; 5-30% water; 2-8% fuel; 0.5-4% emulsifier or thickening agent; 0-10% soluble flame suppressants; and trace additives. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). A copy of the approval must accompany each shipment. 59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter. 151 If this material meets the definition of a flammable liquid in 173.120 of this subchapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard. Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. Filling limits must be in accordance with portable tank special provision TP3. (b) Description of codes for special provisions. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. A4 Liquids having an inhalation toxicity of Packing Group I are not permitted on aircraft. Comments or questions about document content can not be answered by OFR staff. The Table: provides the proper shipping name or directs the user to the preferred proper shipping name; B57 Class 115A tank car tanks used to transport chloroprene must be equipped with a non-reclosing pressure relief device of a diameter not less than 305 mm (12 inches) with a maximum rupture disc pressure of 310 kPa (45 psig). When a plus sign is assigned to mix- b. If not impact resistant, the outer packaging should not be used as the sole means of protecting the battery terminals from damage or short circuiting. N88 Any metal part of a UN pressure receptacle in contact with the contents may not contain more than 65% copper, with a tolerance of 1%. Lighter refills offered for transportation under this entry may not exceed 4 fluid ounces capacity (7.22 cubic inches) or contain more than 65 grams of fuel. Each inner packaging contains not more than 30 mL; b. 119 This substance, when in quantities of not more than 11.5 kg (25.3 pounds), with not less than 10 percent water, by mass, also may be classed as Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). TP12 This material is considered highly corrosive to steel. A37 This entry applies only to a material meeting the definition in 171.8 of this subchapter for self-defense spray. For transportation by aircraft, the provisions of 173.159(b)(2) apply. Specification IBCs and FIBCs are to be secured to a pallet. The requirements of 172.203(m) and 172.505 of this subchapter do not apply. B13 A nonspecification cargo tank motor vehicle authorized in 173.247 of this subchapter must be at least equivalent in design and in construction to a DOT 406 cargo tank or MC 306 cargo tank (if constructed before August 31, 1995), except as follows: a. Packagings equivalent to MC 306 cargo tanks are excepted from the certification, venting, and emergency flow requirements of the MC 306 specification. "Published Edition". Regulation Y Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. d. All inner packagings placed inside bulk outer packagings must be blocked and braced to prevent shifting during transportation that could cause the container to open or fall over. Energy storage capacity means the energy stored in a capacitor, as calculated according to the following equation. For liquids transported under ambient conditions may be calculated using the formula: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. 328 When lithium metal or lithium ion batteries are contained in the fuel cell system, the item must be described under this entry and the appropriate entries for Lithium metal batteries contained in equipment or Lithium ion batteries contained in equipment. 22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 C (122 F). TP16 The portable tank must be protected against over and under pressurization which may be experienced during transportation. W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means. N32 Aluminum materials of construction are not authorized for single packagings. Column 8 N5 Glass materials of construction are not authorized for any part of a packaging which is normally in contact with the hazardous material. In accordance with Special Provision 8 in 172.102, which is referenced in Column 7 of the Hazardous Materials Table (HMT; 172.101) for the entry "UN3082, Environmentally hazardous substance, liquid, n.o.s.," a hazardous substance that is not a hazardous waste may be shipped under the shipping description "Other regulated substances . contact the publishing agency. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. If a tank car tank is equipped with a non-reclosing pressure relief device, the rupture disc must be perforated with a 3.2 mm (0.13 inch) diameter hole. A single packaging of a 4C2 sift-proof, natural wood box; or. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . N11 This material is excepted for the specification packaging requirements of this subchapter if the material is packaged in strong, tight non-bulk packaging meeting the requirements of subparts A and B of part 173 of this subchapter. When a consignment is undeliverable, the consignment shall be placed in a safe location and the appropriate competent authority shall be informed as soon as possible and a request made for instructions on further action. Kits that are carried on board transport vehicles for first aid or operating purposes are not subject to the requirements of this subchapter. In addition, for solid materials, special provision B54 applies. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. and are not subject to requirements of this subchapter except for the following: (a) Incident reporting. (3) When no bottom openings are authorized, the alternative portable tank must not have bottom openings. 49 CFR 172.101 Effective January 1, 2014, for transportation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. 49 U.S.C. Hazardous materials necessary for the safe and proper operation of the cargo transport unit (e.g., fire extinguishing systems and air conditioning systems), must be properly secured to or installed in the cargo transport unit and are not otherwise subject to this subchapter. It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 meters; and. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by 180.605 of this subchapter must be conducted. Pressing enter in the search box Outage must be sufficient to prevent tanks from becoming liquid full at 55 C (130 F). c. The cylinders are collected and transported by a private or a contract carrier for reconditioning, reuse or disposal. For vessel transport, the palletized loads, pallet boxes or unit load devices must be firmly packed and secured in closed cargo transport units; or. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package. For criteria in determining what is a new lighter design, see 173.308(b)(1). TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). Column 7: Special Provisions - Specifies codes for special provisions applicable to some hazardous materials. 49 CFR 173.24 - LII / Legal Information Institute The numbers and letters in the special provisions column are referred to in 49 CFR 172.102 with an explanation of their meanings. This includes hybrid electric vehicles powered by a fuel cell, an internal combustion engine, and wet, sodium or lithium batteries installed. For continued use of approvals dated prior to January 1, 2012, see 173.308(b)(5). TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. The examination and testing of each lighter design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in 173.308(a)(4). 136 This entry applies only to articles, machinery, and apparatus containing hazardous materials as an integral element of the article, machinery, or apparatus. If they do leak, they must be overpacked in packagings conforming to the specification requirements of part 178 of this subchapter or in salvage packagings conforming to the requirements in 173.12 of this subchapter. Thickness of stainless steel for tank shell and heads must be the greater of 7.62 mm (0.300 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.5 times the vapor pressure of the hazardous material at 46 C (115 F). Interpretation Response | PHMSA - Pipeline and Hazardous Materials Where the quantity of hazardous materials contained as an integral element in machinery or apparatus exceeds the limits permitted by 173.222(c)(2), and the hazardous materials meet the provisions of 173.222(c), the machinery or apparatus may be transported by aircraft only with the prior approval of the Associate Administrator. 54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft. This content is from the eCFR and is authoritative but unofficial. For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). 53 Packages of these materials must bear the subsidiary risk label, EXPLOSIVE, and the subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. b. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely surrounded with absorbent cushioning material. The quantities of hazardous materials do not exceed those specified in 173.4a of this subchapter; and. All successfully conducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each authorized mode of transport in this special provision. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. Use the above summary to assist you in reviewing the special provisions applicable to the HazMat you offer for transportation. ; and. Outage must be at least 5 percent at 98 C (208 F). 78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. 128 Regardless of the provisions of 172.101(c)(12), aluminum smelting by-products and aluminum remelting by-products described under this entry, meeting the definition of Class 8, Packing Group II and III may be classed as a Division 4.3 material and transported under this entry. Navigate by entering citations or phrases b. It is shown that it does not pose a significant risk in transportation; b. 145 This entry applies to formulations that neither detonate in the cavitated state nor deflagrate in laboratory testing, show no effect when heated under confinement, exhibit no explosive power, and are thermally stable (self-accelerating decomposition temperature (SADT) at 60 C (140 F) or higher for a 50 kg (110.2 lbs.) N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. After filling, each glass inner packaging must be determined to be leak-tight by placing the glass inner packaging in a hot water bath at a temperature and for a period of time sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 C is achieved. The material is packaged in a DOT Specification 4BW240 cylinder, or in a DOT-51 portable tank. b. Packagings equivalent to DOT 406 cargo tanks are excepted from 178.345-7(d)(5), circumferential reinforcements; 178.345-10, pressure relief; 178.345-11, outlets; 178.345-14, marking, and 178.345-15, certification. 41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings. Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. TABLE 2 lists . 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. These provisions apply only to non-bulk packagings: N3 Glass inner packagings are permitted in combination or composite packagings only if the hazardous material is free from hydrofluoric acid. 175 This substance must be stabilized when in concentrations of not more than 99%. B83 Bottom outlets are prohibited on tank car tanks transporting sulfuric acid in concentrations over 65.25 percent. B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa (300 psig). 107 The classification of the substance is expected to vary especially with the particle size and packaging but the border lines have not been experimentally determined; appropriate classifications should be verified following the test procedures in 173.57 and 173.58 of this subchapter. Heater pipes must be of welded construction designed for a test pressure of 500 psig. citations and headings Testing must be performed or witnessed by a person who is approved by the Associate Administrator (see 173.56(b) of this subchapter). The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. 39 This substance may be carried under provisions other than those of Class 1 only if it is so packed that the percentage of water will not fall below that stated at any time during transport. Choosing an item from 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. Overcharge of the rechargeable lithium ion cells is precluded by design; iii. Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in accordance with the procedures specified in 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter. A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment components must be approved for transport by the Associate Administrator. These mixtures may be classified in Division 4.1 when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) and approved by the Associate Administrator. 146 This description may be used for a material that poses a hazard to the environment but does not meet the definition for a hazardous waste or a hazardous substance, as defined in 171.8 of this subchapter, or any hazard class, as defined in part 173 of this subchapter, if it is designated as environmentally hazardous by another Competent Authority. (6) R codes. A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. TP4 The maximum degree of filling for portable tanks must not exceed 90%. No more than four bottles, securely closed with threaded caps, may be packed in each box. b. Retain a copy of each notification of pilot-in-command if requested for up to 30 days Which one of the following hazardous materials is NOT excepted from the quantity limitations in 175.75? (4) A code containing the letters IB or IP refers to a special provision that applies only to transportation in IBCs. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage. 13 The words Inhalation Hazard shall be entered on each shipping paper in association with the shipping description, shall be marked on each non-bulk package in association with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk package. Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. Each reference in this column to a material which is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter "A" or "W", is modified to include " 173.203" or " 173.213", as appropriate for liquids and solids, respectively, on those occasions when the . 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see 171.7 of this subchapter). A191 Notwithstanding the Division 6.1 subsidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the shipping paper are not required for manufactured articles containing less than 5 kg (11 pounds) of mercury. N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. These notes are explained at the end of each TABLE. 369 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. The Associate Administrator may except from the requirements of this subchapter articles, machinery, and apparatus provided: a. Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label. Please do not provide confidential 55 This device must be approved in accordance with 173.56 of this subchapter by the Associate Administrator. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. Metal: 11A, 11B, 11N, 21A, 21B and 21N, b. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. (5) Each receptacle shall be able to withstand a pressure of 20 bar (2000 kPa) without leakage when the pressure relief device is deactivated. N79 Packages consisting of tightly closed metal inner packagings not over 0.5 kg (1.1 pounds) capacity each, packed in outer wooden or fiberboard boxes, or wooden barrels, are authorized and need not conform to the requirements of part 178 of this subchapter.

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column 7 of the hazardous materials table

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